- Sandby, Paul, R.A., 1730 - 1809
- Sandby, Thomas, R.A., 1723? - 1798
- Sanders, Christopher, R.A., 1905 - 1991
- Sant, James, R.A., 1820 - 1916
- Sargent, John Singer, R.A., 1856 - 1925
- Schilsky, Eric, R.A., 1898 - 1974
- Scott, George Gilbert, R.A., 1811 - 1878
- Scott, Giles Gilbert, R.A., 1880 - 1960
- Scott, William, R.A., 1913 - 1989
- Segonzac, André Dunoyer de, Hon. R.A., 1884 - 1974
- Serres, Dominic, the Elder, R.A., 1722 - 1793
- Shannon, Charles, R.A., 1863 - 1937
- Shaw, Richard Norman, R.A., 1831 - 1912
- Shee, Martin Archer, P.R.A., 1769 - 1850
- Sheppard, Richard, R.A., 1910 - 1982
- Short, Frank, R.A., 1857 - 1945
- Sickert, Walter, R.A., 1860 - 1942
- Sims, Charles, R.A., 1873 - 1928
- Sisson, Marshall, R.A., 1897 - 1978
- Skeaping, John, R.A., 1901 - 1980
- Smirke, Robert, R.A., 1753 - 1845
- Smirke, Robert, R.A., 1780 - 1867
- Smirke, Sydney, R.A., 1798 - 1877
- Smith, Anker, A.R.A., 1759 - 1819
- Smythe, Lionel, R.A., 1839 - 1918
- Soane, John, R.A., 1753 - 1837
- Solomon, Solomon J., R.A., 1860 - 1927
- Spear, Ruskin, R.A., 1911 - 1990
- Spence, Basil, R.A., 1907 - 1976
- Spencer, Gilbert, R.A., 1892 - 1979
- Spencer, Stanley, R.A., 1891 - 1959
- Spurrier, Steven, R.A., 1878 - 1961
- Stacpoole, Frederick, A.R.A., 1813 - 1907
- Stanfield, Clarkson, R.A., 1793 - 1867
- Stephens, Edward, A.R.A., 1815 - 1882
- Stevens, Edward, A.R.A., ca. 1744 - 1775
- Stevens, Norman, A.R.A., 1937 - 1988
- Stirling, James, R.A., 1926 - 1992
- Stocks, Lumb, R.A., 1812 - 1892
- Stokes, Adrian, R.A., 1854 - 1935
- Stone, Frank, A.R.A., 1800 - 1859
- Stone, Marcus, R.A., 1840 - 1921
- Storey, G.A., R.A., 1834 - 1919
- Stothard, Thomas, R.A., 1755 - 1834
- Stott, Edward, A.R.A., 1859 - 1918
- Street, George Edmund, R.A., 1824 - 1881
- Stubbs, George, A.R.A., 1724 - 1806
- Swan, John M., R.A., 1847 - 1910
- Swynnerton, Annie, A.R.A., 1844 - 1933
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